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Chemical Engineering Thermodynamics
DETAILED CONTENTS
Systems, processes and surroundings, homogenous and heterogeneous systems, closed, open and isolated, intensive and extensive properties, state and path functions. Concept of internal energy, enthalpy, entropy, free energy and equilibrium equation of state, ideal gas law, Vander Waals equation. Amagat’s law, Dalton’s law, Henry’s law, Zeroth law of thermodynamics.
2. First Law of Thermodynamics for Open and Closed System. (Marks Allotted 09)
Statement of first law of thermodynamics, use of steam tables, calculation of internal energy, enthalpy, heat and work for ideal gas undergoing reversible, isothermal, Isobaric, adiabatic and polytrophic process. T-V, P-V and P-T diagrams.
3. Second Law of Thermodynamics. (Marks Allotted 12)
Statement of second law of thermodynamics: Kelvin Plank statement and Classius statement, Carnot cycle and its efficiency, concept of entropy and entropy change for closed and open system. Heat pump and heat engine (coefficient of performance and efficiency). Reversible and irreversible process. Thermodynamic temperature scale. Thermal thermodynamic equation, Maxwell relation.
Inequality of Classius, entropy-a property of a system entropy change in reversible process, entropy change for an open system, principle of increase of entropy, efficiency, irreversibility.
6. Applications of Second law of Thermodynamics. (Marks Allotted 06)
Refrigeration, vapor compression and absorption refrigeration cycle, air refrigeration cycle, types of compressors, reciprocating air compressor, single stage compressor, and isentropic efficiency of compressor, coefficient of performance(COP), liquefaction process, latest refrigerantstheir qualities and applications.
7. Chemical Reaction Equilibrium and Vapor Liquid Equilibrium (Marks Allotted 06)
Concept of chemical potential, Gibb’s Duhen Equation, Raoul’s law, Gibb’s phase rule, vapor liquid equilibrium, dew point and bubble point, calculations for two component systems, fugacity, fugacity, fugacity coefficient, activity and activity coefficient.
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